Shinx stands by! is the 11th episode of season 1, in which Ashley and her Pokemon meet a trainer with water Pokemon that has been fighting a group of Luxray, Luxio and Shinx. Afterwards, It turns out that one of the smaller Shinx fights for Ashley, and later on, decides to go with her. Earning Ashley a new team member.
WARNING: May contain plot details and Spoilers
Plot description
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In this episode, Ashley as usual is training hard with her Pokemon, until they hear rustling and a Luxio comes out, and starts randomly attacking them. Luxio takes out Squirtle and Piplup quite easily, but Ashley returns Misdreavus before it can be harmed. A distant yell is heard, and the Luxio runs away, Ashley and her Pokemon meeting a water-type Pokemon trainer named Annabelle. She explains that she's been hunting Luxray, Luxio and Shinx for as long as she could remember, but once Annabelle sees Ashley's two water-type Pokemon, she apologizes for what happened, and asks Ashley for her help in finding the flock once more. Ashley agrees, and brings out Misdreavus to search for the group. Once they do find it however, Annabelle brings out her Marill and Mudkip and begins to violently attack the electric-type Pokemon. But as soon as Misdreavus gets in the way, it gets knocked out of the way of the enraged Annabelle, yelling about how electric-type Pokemon hurt water-pokemon in the area, and deserved to be punished.

Ashley's Shinx friend
Annabelle leaves in a huff of anger to the next town to revive her Pokemon, and Shinx decides to go along with Ashley. Ashley decides to give it a nickname: Shock Girl (In it's actual name a female symbol is seen replacing "Girl") and they continue on their journey to Pastoria city, hoping to find a Pokemon center to help the two water-type Pokemon.
Details
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A Luxio from the pack
The only reason Ashley gave her new shinx a nickname, was because she thought Shinx was boring, and wanted to give Shinx a better title.